Question
Problem 2: 2As+6NaOHarrow 2Na_(3)AsO_(3)+3H_(2) Given: 15 grams of As and 25L NaOH. Which is the excess? arsenic sodium hydroxide sodium arsenite hydrogen gas
Solution
4.4
(204 Votos)
Ramon
Veterano · Tutor por 11 anos
Resposta
To determine which reactant is in excess, we need to calculate the amount of product formed from each reactant and compare them.First, let's calculate the amount of sodium arsenite (Na3AsO3) formed from arsenic (As):Given: 15 grams of AsMolar mass of As = 74.92 g/molNumber of moles of As = 15 g / 74.92 g/mol = 0.200 molAccording to the balanced chemical equation, 2 moles of As produce 2 moles of Na3AsO3. Therefore, 0.200 moles of As will produce 0.200 moles of Na3AsO3.Next, let's calculate the amount of sodium arsenite (Na3AsO3) formed from sodium hydroxide (NaOH):Given: 25 L of NaOHMolar volume of NaOH = 25 LMolar concentration of NaOH = 1 mol/L (assuming 1 M solution)Number of moles of NaOH = 25 L * 1 mol/L = 25 molAccording to the balanced chemical equation, 6 moles of NaOH produce 2 moles of Na3AsO3. Therefore, 25 moles of NaOH will produce (25/6) * 2 = 8.33 moles of Na3AsO3.Comparing the amounts of Na3AsO3 formed from each reactant, we can see that the amount formed from arsenic (0.200 moles) is less than the amount formed from sodium hydroxide (8.33 moles). Therefore, arsenic is the limiting reactant, and sodium hydroxide is in excess.Answer: sodium hydroxide