Question
10. 0.01 mol of HCl were added to 1 Lofa buffer solution containing 0.08 mol of CH_(3)COOH and 0.04 mol of CH_(3)COONa. Calculate the pH of the resulting solution (forCH_(3)COOHpK_(a)=4.76) . (round up the number to the nearest tenth) square
Solution
4.3
(198 Votos)
Erika
Veterano · Tutor por 10 anos
Resposta
To calculate the pH of the resulting solution, we can use the Henderson-Hasselbalch equation, which is given by:
where:-
is the negative logarithm of the acid dissociation constant (
) of the acid.-
is the concentration of the conjugate base.-
is the concentration of the acid.Given:-
for
= 4.76- Initial concentration of
= 0.08 mol- Initial concentration of
(conjugate base) = 0.04 mol- Amount of
added = 0.01 molFirst, we need to determine the new concentrations of
and
after adding
.Since
is a strong acid, it will dissociate completely in water, providing
ions. The
ions will react with the conjugate base (
) to form more
:
The new concentrations will be:- New concentration of
= Initial concentration of
+ amount of
added
- New concentration of
= Initial concentration of
- amount of
added
Now, we can plug these values into the Henderson-Hasselbalch equation:
Calculate the ratio inside the logarithm:
Now, calculate the logarithm:
Finally, add this value to the
:
Rounding to the nearest tenth:
So, the pH of the resulting solution is approximately 4.3.